Column: Electric dreams turn into a nightmare for battery metals
A sector that was once racing to build new supply has been closing mines and deferring projects as low prices bite into the cost curve.
Researchers at the Chinese Academy of Sciences have come up with a new mechanism that overcomes next-gen lithium battery decay.
In a paper published in the Journal of the American Chemical Society, the team explains that in high-voltage lithium batteries using layered transition metal oxide cathodes, the chemical degradation of the electrolytes results in rapid decay of the batteries’ capacity, which poses substantial challenges to practical applications of these devices.
This chemical degradation of the electrolytes is caused during the cycling of the circuit by oxidation of highly reactive oxygen and by an attack of free radicals —any atom, molecule, or ion with an unpaired valence (outer layer) electron.
To address this issue, the researchers started paying attention to certain natural processes where oxygen plays a role in causing degradation. An apple browning, a lump of iron rusting and skin ageing are all in part a product of oxidation ‘damage.’
And nature has come up with all sorts of solutions to counter this problem. Organisms often produce different types of enzymes that work to scavenge active oxygen and free radicals to alleviate the issue.
“So, we thought, why not just try to replicate what nature already does, and put it inside a battery instead?” Cui Guanglei, lead author of the study, said in a media statement.
The researchers then developed a photostabilizer—a fairly simple, anti-ageing binder additive to the electrolyte that can scavenge the singlet oxygen atoms and free radicals.
Through experimental investigation and theoretical calculation, they found that this bio-inspired oxygen scavenging mechanism in layered transition metal oxides-based lithium batteries delivered superior electrochemical performance, even under elevated temperatures.
“This heralds a new paradigm for manipulating the cathode and electrolyte chemistry of all sorts of rechargeable batteries involving chemical degradation of the electrolyte,” Cui said.
Following on from the photostabilizer success, the researchers aim to commercialize high-voltage layered oxide cathode-based lithium batteries with their bio-inspired anti-ageing binder as the next generation of energy storage devices beyond traditional lithium-ion technology.
Comments
Peter Hatgelakas
The oxygen scavenger is a layer of reduction buffers.
That is nothing new at all. In fact it has been in application for the better half of 100 years even though the young people in China are just getting to know the application. That’s Ok, the important thing is that they are trying to be creative and applying thought.